Room-Temperature Plasticity of Refractory Transition-Metal Carbides by Professor Jenn-Ming Yang
NTU MSE Seminar Hosted by Professor Lee Pooi See
Abstract
Refractory carbides of transition metals (e.g., Zr, Ta and Hf) exhibit a unique combination of high hardness, high elastic moduli, excellent wear resistance, and good resistance to ablation and corrosion due to their mix of ionic, covalent, and metallic bonding. These characteristics make them highly suitable for applications in environments involving high temperatures, chemical reactivity, and intense radiation, including in structural, energy, and semiconductor fields. However, despite their hardness, their use in structural applications at low temperatures has been limited by their brittleness. The design of refractory carbides that combine high hardness with enhanced ductility has been a long-standing challenge. Here, we present a brief review of our findings from in-situ observations of mechanical deformation in single crystals of transition-metal carbides (such as ZrC, TaC, VC and SiC) during uniaxial compression, observed directly inside a TEM and SEM. Density function theory calculations were also conducted to identify the most energetically favorable slip systems and the mechanisms governing the plastic deformation. Our studies offer new insights into the deformation mechanisms of these materials and identify potential strategies for enhancing their room-temperature plasticity.
Biography
Professor Jenn-Ming Yang
Distinguished Collins Aerospace Chair of Excellence
Department of Materials Science and Engineering
University of California